The collection primarily consists of the Maunders' published works both on their research and explanatory works on astronomy for a more popular audience. Some of these publications bear annotations. There are also some notes on a variety of subjects, a pin-hole camera, a planisphere and some items of correspondence. There is supporting material in the form of obituaries, letters of condolence and subsequent published works on the Maunders and their work.

Bound volumes of printed Greenwich Heliographic Results, covering the years 1892-1957. Most contain multiple issues of printed results of measures made at the Royal Observatory, Greenwich, of photographs of the Sun taken at Greenwich, the Cape, and Kodaikanal/Mauritius, with additions such as printed ledgers of sunspot groups. The volumes are numbered 6-29. Numbers 1-5 are not extant.